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2-Amino-5-mercaptothiadiazole

2-Amino-5-mercaptothiadiazole

  • 2-Amino-5-mercapto-1,3,4-thiadiazole
  • 2-Amino-1,3,4-thiadiazole-5-mercaptan
  • 5-Amino-2-mercapto-1,3,4-thiadiazole
  • 5-Amino-1,3,4-thiadiazoline-2-thione
  • 5-Amino-1,3,4-thiadiazole-2-thiol
  • 5-Amino-1,3,4-thiadiazole-2(3H)-thione
FormulaC2H3N3S2 (C2H3N3S2)
Description White powder.

Registry Numbers and Inventories.
CAS2349-67-9
EC (EINECS/ELINCS)219-078-4
EC Risk PhraseR:22
EC Safety PhraseS:22-36/37
ENCS (MITI) 5-570
RTECSXI4550000
RTECS class Z Other (Z)
UN (DOT)2811
Beilstein ref.4-27-00-08185
Listed on the Toxic Substancs Control Act (TSCA).
Listed on Canadian Domestic Substances List (DSL).
Listed on Australian Inventory of Chemical Substances (AICS).

Properties.
Formula mass133.19
Melting point, °C245
Solubility in waterVery soluble
Acid/Base6.94 (pka)

Hazards and Protection.
Storage Store in a cool, dry place. Keep container closed when not in use. Store in a tightly closed container. Store in a cool, dry, well-ventilated area away from incompatible substances.
Handling Wash thoroughly after handling. Remove contaminated clothing and wash before reuse. Avoid contact with eyes, skin, and clothing. Keep container tightly closed. Avoid ingestion and inhalation. Use with adequate ventilation. Wash clothing before reuse.
Protection Eyes: Wear safety glasses and chemical goggles if splashing is possible. Wear appropriate protective eyeglasses or chemical safety goggles as described by OSHA's eye and face protection regulations in 29 CFR 1910.133 or European Standard EN166. Skin: Wear appropriate protective gloves and clothing to prevent skin exposure. Wear appropriate protective gloves to prevent skin exposure. Clothing: Wear appropriate protective clothing to minimize contact with skin. Wear appropriate protective clothing to prevent skin exposure.
Respirators A respiratory protection program that meets OSHA's 29 CFR 1910.134 and ANSI Z88.2 requirements or European Standard EN 149 must be followed whenever workplace conditions warrant a respirator's use. Wear a NIOSH/MSHA or European Standard EN 149 approved full-facepiece airline respirator in the positive pressure mode with emergency escape provisions.
Small spills/leaks Clean up spills immediately, using the appropriate protective equipment. Sweep up, then place into a suitable container for disposal. Sweep up or absorb material, then place into a suitable clean, dry, closed container for disposal. Provide ventilation.
Stability Stable under normal temperatures and pressures.
Incompatibilities Strong oxidizing agents.
Decomposition Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

Fire.
Fire fighting Wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear. During a fire, irritating and highly toxic gases may be generated by thermal decomposition or combustion. To extinguish fire, use water, dry chemical, chemical foam, or alcohol-resistant foam. In case of fire use water spray, dry chemical, carbon dioxide, or appropriate foam.

Health.
Exposure effectsEffects may be delayed.
Ingestion
May cause gastrointestinal irritation with nausea, vomiting and diarrhea.
Inhalation
Causes respiratory tract irritation. Can produce delayed pulmonary edema.
Skin
Causes skin irritation.
First aid 
Ingestion
Never give anything by mouth to an unconscious person. Get medical aid. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation
Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Skin
Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Wash clothing before reuse.

UN number2811
Response guide

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